Back to Search Start Over

catena-Poly[[[aqua[3-(2-pyridylsulfanyl)propionato N-oxide-κ O1]copper(II)]-μ-[3-(2-pyridylsulfanyl)propionato N-oxide-κ3 O3: O1, O1′] dihydrate].

Authors :
Indrani, Murugan
Ramasubramanian, Ramasamy
Kumaresan, Sudalaiandi
Mao-Lin Hu
Soriano-García, Manuel
Source :
Acta Crystallographica: Section C (Wiley-Blackwell); Jan2008, Vol. 64 Issue 1, pm23-m25, 1p, 2 Diagrams, 2 Charts
Publication Year :
2008

Abstract

In the title complex, {[Cu(C<subscript>8</subscript>H<subscript>8</subscript>NO<subscript>3</subscript>S)<subscript>2</subscript>(H<subscript>2</subscript>O)]·2H<subscript>2</subscript>O}<subscript> n</subscript>, the Cu<superscript>II</superscript> cation has a distorted square-pyramidal coordination environment consisting of five O atoms, one from a water molecule, one from an N—O group and the other three from the carboxylate groups of two 3-(2-pyridylsulfanyl)propionate N-oxide anions. The aqua[3-(2-pyridylsulfanyl)propionato N-oxide]copper(II) moieties are bridged by 3-(2-pyridylsulfanyl)propionate N-oxide anions to form an infinite three-dimensional coordination polymer with a zigzag chain structure. The crystal structure is stabilized by hydrogen bonds. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
01082701
Volume :
64
Issue :
1
Database :
Complementary Index
Journal :
Acta Crystallographica: Section C (Wiley-Blackwell)
Publication Type :
Academic Journal
Accession number :
28807998
Full Text :
https://doi.org/10.1107/S0108270107051670