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Structurally different cadmium(II) and lead(II) supramolecular polymers with the same benzene-1,2,3,4-tetracarboxylate dianion as bridging ligands from hydrothermal reactions.
- Source :
- Journal of Coordination Chemistry; May2008, Vol. 61 Issue 9, p1437-1442, 6p, 4 Diagrams, 2 Charts
- Publication Year :
- 2008
-
Abstract
- Two crystalline metal-organic frameworks, [Cd2(o-BTC)(H2O)2]n (1) and [Pb2(o-BTC)]n (2) (o-BTC = benzene-1,2,3,4-tetracarboxylic), were synthesized under hydrothermal conditions and characterized by analytical, spectroscopic and single crystal X-ray diffraction studies, which reveal three-dimensional reticular structures via M2+ and carboxylate ligands. All carboxyl groups of o-BTC are deprotonated, in agreement with the IR data. The Cd2+ centers of 1 have one coordination environment, while Pb2+ centers of 2 have two coordination environments. Both 1 and 2 form 3D interpenetrated grid structures along the b and c axes, respectively. [ABSTRACT FROM AUTHOR]
- Subjects :
- BIOSYNTHESIS
CADMIUM
LEAD
X-ray diffraction
LIGANDS (Chemistry)
Subjects
Details
- Language :
- English
- ISSN :
- 00958972
- Volume :
- 61
- Issue :
- 9
- Database :
- Complementary Index
- Journal :
- Journal of Coordination Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 31963500
- Full Text :
- https://doi.org/10.1080/00958970701579308