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Controllable preparation of ZnII coordination polymers: unusual solvothermal formation of a LiGe-type framework directed by in situ S–S coupling of 5-(4-pyridyl)-1H-1,2,4-triazole-3-thiol.
- Source :
- Chemical Communications; Mar2008, Vol. 2008 Issue 11, p1296-1298, 3p
- Publication Year :
- 2008
-
Abstract
- Controlled assembly of ZnII with a versatile ligand 5-(4-pyridyl)-1H-1,2,4-triazole-3-thiol (Hptt) in conventional or solvothermal condition affords two distinct coordination frameworks, in which the former shows a unique 3-D pseudo-polyrotaxane architecture with 1-D water tapes penetrating the 2-D Zn–ptt layers, whereas the later is generated from in situ S–S coupling of Hptt and has a very rare 2-fold interpenetrating LiGe (lig) topology. [ABSTRACT FROM AUTHOR]
- Subjects :
- POLYMERS
LIGANDS (Chemistry)
THIOLS
ORGANOSULFUR compounds
Subjects
Details
- Language :
- English
- ISSN :
- 13597345
- Volume :
- 2008
- Issue :
- 11
- Database :
- Complementary Index
- Journal :
- Chemical Communications
- Publication Type :
- Academic Journal
- Accession number :
- 32609540
- Full Text :
- https://doi.org/10.1039/b716461k