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Rationally Designing Molecularly Imprinted Polymer Toward a High Specific Recognition by Using a Stoichiometric Self-Assembly.
- Source :
- Polymer-Plastics Technology & Engineering; Sep2008, Vol. 47 Issue 9, p936-942, 7p, 3 Diagrams, 8 Graphs
- Publication Year :
- 2008
-
Abstract
- This article presents an original work aimed at rationally designing a molecularly imprinted polymer capable of a high specific recognition. Assembling with Bisphenol A as template and acrylamide as functional monomer, the imprinted polymer was prepared. The results indicate that the use of stoichiometric self-assembly plays an obvious role on significantly increasing the specificity of prepared material, so as to better discriminate the template from its analogue. A higher or lower extent of molecular self-assembly would result in a dramatic decrease in this specificity. Related information indicates that this, logically, can be a result of the increasing match between binding sites and the template, which makes the polymer capable of specifically recognizing the imprint species. [ABSTRACT FROM AUTHOR]
- Subjects :
- MOLECULAR imprinting
POLYMERIZATION
POLYMERS
BISPHENOL A
PHENOLS
MONOMERS
Subjects
Details
- Language :
- English
- ISSN :
- 03602559
- Volume :
- 47
- Issue :
- 9
- Database :
- Complementary Index
- Journal :
- Polymer-Plastics Technology & Engineering
- Publication Type :
- Academic Journal
- Accession number :
- 33716739
- Full Text :
- https://doi.org/10.1080/03602550802274522