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Aryl bromide/triflate selectivities reveal mechanistic divergence in palladium-catalysed couplings; the Suzuki–Miyaura anomalyElectronic supplementary information (ESI) available: Experimental details. See DOI: 10.1039/b701517h.

Authors :
Gustavo Espino
Almira Kurbangalieva
John M. Brown
Source :
Chemical Communications; Apr2007, Vol. 2007 Issue 17, p1742-1744, 3p
Publication Year :
2007

Abstract

In palladium-catalysed cross-coupling reactions, the outcome of competition between aryl bromides and aryl triflates depends on the nucleophilic partner; Suzuki couplings with R–B generally follow a different pattern from other R–M species. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
13597345
Volume :
2007
Issue :
17
Database :
Complementary Index
Journal :
Chemical Communications
Publication Type :
Academic Journal
Accession number :
36326643
Full Text :
https://doi.org/10.1039/b701517h