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Vibrational spectra and electron detachment energy of the anionic water hexamer.
- Source :
- Journal of Chemical Physics; 10/1/2000, Vol. 113 Issue 13, 12 Diagrams, 1 Chart, 8 Graphs
- Publication Year :
- 2000
-
Abstract
- A number of experimental and theoretical studies have been carried out on the anionic water hexamer in the last decade. However, none of these studies have reported the adiabatic electron detachment energy. The present study employing extensive high-level ab initio calculations report the adiabatic electron detachment energy, which explains the unusual stability of the anionic water hexamer. This stability can be correlated to the unusually intense peak observed in the photoelectron-detachment spectra. It is also shown that our previously predicted pyramid structure reproduces the important characteristics of the experimental O-H vibrational spectra. © 2000 American Institute of Physics. [ABSTRACT FROM AUTHOR]
- Subjects :
- VIBRATIONAL spectra
ELECTRON energy loss spectroscopy
Subjects
Details
- Language :
- English
- ISSN :
- 00219606
- Volume :
- 113
- Issue :
- 13
- Database :
- Complementary Index
- Journal :
- Journal of Chemical Physics
- Publication Type :
- Academic Journal
- Accession number :
- 4410889
- Full Text :
- https://doi.org/10.1063/1.1290018