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Organopalladium and platinum chemistry in oxidising milieu as models for organic synthesis involving the higher oxidation states of palladium.
- Source :
- Dalton Transactions: An International Journal of Inorganic Chemistry; Nov2009, Vol. 2009 Issue 47, p10409-10417, 9p
- Publication Year :
- 2009
-
Abstract
- This perspective focuses on the higher oxidation state (iii, iv) organometallic chemistry of palladium involving a range of strong oxidants, with consideration of platinum chemistry where it is informative for the evaluation of structure and mechanism. Particular emphasis is placed on hypervalent iodine reagents, halogens and related oxidants of intense current interest in organic synthesis, together with linkages in concepts between this chemistry and recent advances in studies of diaryl disulfides, diaryl diselenides, and diaryl peroxides as oxidants. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 14779226
- Volume :
- 2009
- Issue :
- 47
- Database :
- Complementary Index
- Journal :
- Dalton Transactions: An International Journal of Inorganic Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 45528134
- Full Text :
- https://doi.org/10.1039/b914080h