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A zirconium methacrylate oxocluster as precursor for the low-temperature synthesis of porous zirconium(IV) dicarboxylates.

Authors :
Guillerm, Vincent
Gross, Silvia
Serre, Christian
Devic, Thomas
Bauer, Matthias
Férey, Gérard
Source :
Chemical Communications; Feb2010, Vol. 46 Issue 5, p767-769, 3p
Publication Year :
2010

Abstract

The exchange of the monocarboxylate ligand of the zirconium methacrylate oxocluster Zr6O4(OH)4(OMc)12(OMc = CH2CH(CH3)COO) with dicarboxylic acids (trans,transmuconic acid and terephthalic acid) leads to porous zirconium dicarboxylates exhibiting the UiO-66 architecture; the mild reaction conditions allow the control of their particle size. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
13597345
Volume :
46
Issue :
5
Database :
Complementary Index
Journal :
Chemical Communications
Publication Type :
Academic Journal
Accession number :
47751737
Full Text :
https://doi.org/10.1039/b914919h