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Kinetic Study of Oxidation of Valine by N-bromophthalimide in Presence of Iridium (III) Chloride as Homogenous Catalyst.
- Source :
- Synthesis & Reactivity in Inorganic, Metal-Organic, & Nano-Metal Chemistry; Feb2010, Vol. 40 Issue 2, p71-77, 7p, 1 Diagram, 5 Charts, 5 Graphs
- Publication Year :
- 2010
-
Abstract
- The mechanistic study of Ir(III) chloride catalyzed oxidation of Val has been studied by by N-bromophthalimide (NBP) in aqueous perchloric acid medium at 303 K. The reaction followed first order kinetics with respect to [NBP] and zero order kinetics with respect to [Val]. At lower concentration range of Ir(III) chloride, the reaction followed first order kinetics while tending to zero order at its higher concentration. A negative effect was observed for [H+] and [NHP] (phthalimide) whereas variation in [Hg(OAc)2] (mercuric acetate), [Cl-], ionic strength (I) and dielectric constant of the medium did not bring about any significant change on the rate of reaction. The rate constants observed at five different temperatures (298 K-318 K) were used to calculate the activation parameters. A plausible mechanism from the results of kinetic studies, reaction stoichiometry and product analysis has been proposed. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 15533174
- Volume :
- 40
- Issue :
- 2
- Database :
- Complementary Index
- Journal :
- Synthesis & Reactivity in Inorganic, Metal-Organic, & Nano-Metal Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 48149748
- Full Text :
- https://doi.org/10.3109/10799890903555681