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Synthesis, structure and nonlinear optical properties of two novel two-photon absorption chromophores.
- Source :
- Science in China. Series B: Chemistry; Apr2009, Vol. 52 Issue 4, p529-534, 6p
- Publication Year :
- 2009
-
Abstract
- Two triphenylamine-based derivatives that can be used as two-photon absorption chromophore, tris{4-[4-(3-trifluoromethyl-3-oxopanoyl)]phenyl}amine (1) and tris{4-[4-(3-phenyl-3-oxopanoyl)] phenyl} amine (2) were successfully synthesized and fully characterized by elemental analysis, IR, <superscript>1</superscript>H NMR and MS. The single crystal X-ray diffraction analysis showed that the molecules possess D-(π-A)<subscript>3</subscript> structures. One-and two-photon absorption and fluorescence in various solvents were experimentally investigated. A data recording experiment proved the potential application of these chromophores. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 10069291
- Volume :
- 52
- Issue :
- 4
- Database :
- Complementary Index
- Journal :
- Science in China. Series B: Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 49374222
- Full Text :
- https://doi.org/10.1007/s11426-009-0026-y