Back to Search
Start Over
Hydrosilylation catalysed by a rhodium complex in a supercritical CO2/ionic liquid system.
- Source :
- New Journal of Chemistry; Jul2010, Vol. 34 Issue 7, p1330-1334, 5p
- Publication Year :
- 2010
-
Abstract
- The hydrosilylation of alkenes in a supercritical CO2(scCO2)/ionic liquid (IL) system was investigated. Rh(PPh3)3Cl exhibited excellent catalytic activity and selectivity. KOtBu was used as an additive, and no hydrogenation by-product (alkane) was detected in the scCO2/IL system. During hydrosilylation in the scCO2/IL system, the reactants were possibly transferred into the IL phase by scCO2, in which the catalyst was dissolved. The products can be flushed with scCO2after the reaction and the catalyst/IL system reused. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 11440546
- Volume :
- 34
- Issue :
- 7
- Database :
- Complementary Index
- Journal :
- New Journal of Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 52341631
- Full Text :
- https://doi.org/10.1039/c0nj00012d