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Communication: Relationships between Intermolecular potential, thermodynamics, and dynamic scaling in viscous systems.

Authors :
Grzybowski, A.
Paluch, M.
Grzybowska, K.
Haracz, S.
Source :
Journal of Chemical Physics; 10/28/2010, Vol. 133 Issue 16, p161101, 4p, 1 Chart
Publication Year :
2010

Abstract

In this communication, we provide a recipe for a consistent relation between dynamic scaling and thermodynamic properties well-grounded by the same intermolecular generalized Lennard-Jones potential, which is derived by using an essentially modified Avramov model within the framework of the 'thermodynamic scaling' idea. This relation is experimentally verified very well for supercooled van der Waals liquids, and consequently, it can be a good basis for a proper universal description of molecular dynamics and thermodynamics of viscous systems. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
00219606
Volume :
133
Issue :
16
Database :
Complementary Index
Journal :
Journal of Chemical Physics
Publication Type :
Academic Journal
Accession number :
54858566
Full Text :
https://doi.org/10.1063/1.3496999