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Control of structure formation in phase-separating systems.

Authors :
Singh, Awaneesh
Mukherjee, A.
Vermeulen, H. M.
Barkema, G. T.
Puri, Sanjay
Source :
Journal of Chemical Physics; 1/28/2011, Vol. 134 Issue 4, p044910, 8p
Publication Year :
2011

Abstract

In this paper, we study the evolution of phase-separating binary mixtures which are subjected to alternate cooling and heating cycles. An initially homogeneous mixture is rapidly quenched to a temperature T<subscript>1</subscript><T<subscript>c</subscript>, where T<subscript>c</subscript> is the critical temperature. The mixture undergoes phase separation for a while and is then suddenly heated to a temperature T<subscript>2</subscript>>T<subscript>c</subscript>. These cycles are repeated to create a domain morphology with multiple length scales, i.e., the structure factor is characterized by multiple peaks. For phase separation in d = 2 systems, we present numerical and analytical results for the emergence and growth of this multiple-scale morphology. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
00219606
Volume :
134
Issue :
4
Database :
Complementary Index
Journal :
Journal of Chemical Physics
Publication Type :
Academic Journal
Accession number :
57679478
Full Text :
https://doi.org/10.1063/1.3530784