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Syntheses, crystal structures, and spectral properties of Mn(II) and Co(II) complexes with 3-(p-chlorophenyl)- 4-(p-methylphenyl)-5-(2-pyridyl)-1,2,4-triazole.
- Source :
- Journal of Coordination Chemistry; Mar2011, Vol. 64 Issue 6, p942-951, 10p, 5 Diagrams, 4 Charts, 1 Graph
- Publication Year :
- 2011
-
Abstract
- Two new complexes, trans-[MnL2(NCS)2] (1) and trans-[CoL2(H2O)(EtOH)](ClO4)2 · H2O (2) with asymmetrical triaryltriazole ligands [L = 3-(p-chlorophenyl)-4-(p-methylphenyl)-5-(2-pyridyl)-1,2,4-triazole], have been synthesized and characterized by elemental analysis, FT-IR, ESI-MS, and single-crystal X-ray diffraction. In the complexes each L adopts a chelating bidentate mode via the nitrogen of pyridyl and triazole. Both complexes have a similar distorted octahedral core with two NCS- ions in the trans position in 1, while one H2O and one EtOH are present in the axial sites in 2. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 00958972
- Volume :
- 64
- Issue :
- 6
- Database :
- Complementary Index
- Journal :
- Journal of Coordination Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 58667418
- Full Text :
- https://doi.org/10.1080/00958972.2011.558897