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[5-Bromo- N-(2-carboxylatophenyl)salicylideniminato]dimethyltin(IV).
- Source :
- Acta Crystallographica: Section C (Wiley-Blackwell); Apr2002, Vol. 58 Issue 4, pm266-m267, 1p
- Publication Year :
- 2002
-
Abstract
- The structure of the title di­methyl­tin(IV) complex, [2-(5-bromo-2-oxido­benzyl­idene­amino)­benzoato-κ<superscript>3</superscript> O, N, O′]di­methyl­tin(IV), [Sn(CH<subscript>3</subscript>)<subscript>2</subscript>(C<subscript>14</subscript>H<subscript>8</subscript>BrNO<subscript>3</subscript>)], features centrosymmetric dimers disposed about a central Sn<subscript>2</subscript>O<subscript>2</subscript> core. Each Sn centre has seven-coordinate pentagonal-bipyramidal geometry, taking into account two moderately long Sn-O contacts about an inversion centre [2.679 (4) and 2.981 (4) Å]. The methyl groups are in an axial orientation. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 01082701
- Volume :
- 58
- Issue :
- 4
- Database :
- Complementary Index
- Journal :
- Acta Crystallographica: Section C (Wiley-Blackwell)
- Publication Type :
- Academic Journal
- Accession number :
- 63601807
- Full Text :
- https://doi.org/10.1107/S0108270102003530