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Theoretical modeling on the kinetics of the arsenate-ester hydrolysis: implications to the stability of As-DNAElectronic supplementary information (ESI) available: Cartesian coordinates of the computed models. See DOI: 10.1039/c1cp20423h.
- Source :
- Physical Chemistry Chemical Physics (PCCP); May2011, Vol. 13 Issue 23, p10869-10871, 3p
- Publication Year :
- 2011
-
Abstract
- Quantum chemical calculations reveal that neither steric hindrance nor less polar solvent medium is able to reduce the otherwise high hydrolysis rate of arsenate-esters. These results question the stability of As-DNA not only in aqueous but also in non-aqueous environments. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 14639076
- Volume :
- 13
- Issue :
- 23
- Database :
- Complementary Index
- Journal :
- Physical Chemistry Chemical Physics (PCCP)
- Publication Type :
- Academic Journal
- Accession number :
- 63607688