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Two New Salts Based on Bis(nitriledithiolate)nickelate Anion with Substituted 2-Aminopyridinium: Syntheses, Crystal Structures, and Properties.
- Source :
- Synthesis & Reactivity in Inorganic, Metal-Organic, & Nano-Metal Chemistry; Aug2011, Vol. 41 Issue 7, p845-851, 7p
- Publication Year :
- 2011
-
Abstract
- Two new salts, [1-NaMe-2-NH2Py]2[Ni(mnt)2] (1) and [1-NaMe-2-NH2Py]2[Ni(i-mnt)2] (2) ([1-NaMe-2-NH2Py]+ = 1-(1'-naphthylmethyl)-2-aminopyridinium, mnt2- = maleonitriledithiolate, and i-mnt2- = iso-maleonitriledithiolate), have been obtained and characterized by elemental analyses, infrared (IR), ultraviolet (UV), mass spectroscopy (MS), molar conductivities, and single-crystal x-ray diffraction. The results have shown that the change of the ligand from mnt to i-mnt results in differences in the crystal system, space group, weak interactions, and the stacking mode of the cations and anions. The effects of weak interactions such as C--H···N, N-H···N, or C--H···Ni hydrogen bonds and p···π, π···π, and C--H···π stacking interactions generate a three-dimensional (3D) network structure. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 15533174
- Volume :
- 41
- Issue :
- 7
- Database :
- Complementary Index
- Journal :
- Synthesis & Reactivity in Inorganic, Metal-Organic, & Nano-Metal Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 64319788
- Full Text :
- https://doi.org/10.1080/15533174.2011.591313