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A doubly end-on azido-bridged trinuclear Cu(II) complex: synthesis, spectral and DFT functional studies.
- Source :
- Journal of Chemical Research; 2011, Vol. 35 Issue 3, p140-143, 4p, 3 Diagrams, 2 Charts
- Publication Year :
- 2011
-
Abstract
- A trinuclear, doubly azido-bridged Cu(II) complex, [Cu<subscript>1.50</subscript>(L)(N<subscript>3</subscript>)<subscript>3</subscript>(CH<subscript>3</subscript>OH)]<subscript>2</subscript>, (LH = [(CH<subscript>3</subscript>)<subscript>2</subscript>NCH<subscript>2</subscript>CH<subscript>2</subscript>N=CHC<subscript>6</subscript>H<subscript>3</subscript>(OH) (OMe)]), has been synthesised and fully characterised by elemental analyses, IR, UV-Vis, EPR and DFT studies. Its single crystal X-ray structure reveals that adjacent Cu<superscript>II</superscript> ions are linked by double end-on azido-bridges; thus the full molecule is generated by the site symmetry of a crystallographic two-fold rotation axis. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 17475198
- Volume :
- 35
- Issue :
- 3
- Database :
- Complementary Index
- Journal :
- Journal of Chemical Research
- Publication Type :
- Academic Journal
- Accession number :
- 74021072
- Full Text :
- https://doi.org/10.3184/174751911X12972790588178