Thermal decomposition behavior, kinetics, and thermal hazard evaluation of CMDB propellant containing CL-20 by microcalorimetry.

The thermal decomposition behavior of composite modified double-base propellant containing hexanitrohexaazaisowurtzitane (CL-20/CMDB propellant) was studied by microcalorimetry. The kinetic and thermodynamic parameters were obtained from the analysis of the heat flow curves. The effect of different proportion of CL-20 to the thermal decomposition behavior, kinetics, and thermal hazard was investigated at the same time. The critical temperature of thermal explosion ( T), the self acceleration decomposition temperature ( T), and the adiabatic decomposition temperature rise (Δ T) were calculated to evaluate the thermal hazard of the CL-20/CMDB propellant. It shows that the CMDB propellant with 38% CL-20 has relative lower values of E and lg A, and with 18% CL-20 has the highest potential hazard. [ABSTRACT FROM AUTHOR]