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Improved and delayed radiative emission response of Eu-doped BaTiO3 nanoscale system.
- Source :
- European Physical Journal - Applied Physics; Jul2012, Vol. 59 Issue 1, pN.PAG, 1p
- Publication Year :
- 2012
-
Abstract
- We report on the structural, spectroscopic and radiative emission characteristics of Eu-doped BaTiO3 (BT) nanosystem as compared to the pure BT system. The structural analysis was performed by X-ray diffraction (XRD) studies where the nanoscale BT sample exhibits a perovskite structure with most intense peak along (1 1 0) plane that depicts the preferred crystallographic orientation. Also, the diffraction peak intensity was found to be suppressed for Eu-doped BT nanosystem. The nature of radiative emission was evaluated via steady-state photoluminescence spectroscopy (PL) and positron annihilation spectroscopy (PAS). The improved radiative emission response, with Eu2+ doping, was believed to be accompanied by 4f65d→4f7 transitions in case of Eu-doped BT system. Whereas, PAS lifetime study of doped sample has revealed longer lifetimes indicating thereby partial substitution of Ti4+ by Eu2+ in BaTiO3 system. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 12860042
- Volume :
- 59
- Issue :
- 1
- Database :
- Complementary Index
- Journal :
- European Physical Journal - Applied Physics
- Publication Type :
- Academic Journal
- Accession number :
- 84306004
- Full Text :
- https://doi.org/10.1051/epjap/2012120110