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Quantum-chemical study of organic reaction mechanisms: I. Addition of selenium dihalides to the double bond of vinyl ethers.
- Source :
- Russian Journal of Organic Chemistry; Apr2013, Vol. 49 Issue 4, p508-515, 8p, 5 Diagrams, 1 Chart, 2 Graphs
- Publication Year :
- 2013
-
Abstract
- The mechanism of addition of selenium dihalides to vinyl ethers was studied at the B3LYP/6-311+G( d, p) level of theory. The reaction goes in two steps through seleniranium intermediate. High selectivity of the addition is ensured by consistent effects of the charge and orbital factors. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 10704280
- Volume :
- 49
- Issue :
- 4
- Database :
- Complementary Index
- Journal :
- Russian Journal of Organic Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 87583595
- Full Text :
- https://doi.org/10.1134/S1070428013040039