Design and Synthesis of Chiral Oxathiozinone Scaffolds: Efficient Synthesis of Hindered Enantiopure Sulfinamides and Sulfinyl Ketimines.

Authors :: Han, Zhengxu S.
Herbage, Melissa A.
Mangunuru, Hari P. R.
Xu, Yibo
Zhang, Li
Reeves, Jonathan T.
Sieber, Joshua D.
Li, Zhibin
DeCroos, Philomen
Zhang, Yongda
Li, Guisheng
Li, Ning
Ma, Shengli
Grinberg, Nelu
Wang, Xiaojun
Goyal, Navneet
Krishnamurthy, Dhileep
Lu, Bruce
Song, Jinhua J.
Wang, Guijun
Source :: Angewandte Chemie International Edition; Jun2013, Vol. 52 Issue 26, p6713-6717, 5p
Publication Year :: 2013
Abstract: Is that SO? The title scaffolds have a highly active and properly differentiated SO bond for the efficient synthesis of enantiopure sulfinamides. The method is practical, green, and has the potential to provide an economical commercial process for the synthesis of bulky sulfinamides. [ABSTRACT FROM AUTHOR]

Subjects :: KETONE synthesis
SULFINYL compounds
ALKYL compounds
SULFINAMIDES
IMINES

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