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The Iminyl Radical O2SN.
- Source :
- Angewandte Chemie International Edition; Jul2013, Vol. 52 Issue 31, p7981-7984, 4p
- Publication Year :
- 2013
-
Abstract
- The novel iminyl radical O2SN, a SO3 analogue, was produced by flash vacuum pyrolysis of gaseous alkyl sulfonyl azides RSO2N3 (R=CF3, CH3) mixed with argon. Photoisomerization (λ>360 nm) of O2SN into planar syn‐OSNO and anti‐OSNO (see picture) was observed in solid noble‐gas matrices. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 14337851
- Volume :
- 52
- Issue :
- 31
- Database :
- Complementary Index
- Journal :
- Angewandte Chemie International Edition
- Publication Type :
- Academic Journal
- Accession number :
- 89305401
- Full Text :
- https://doi.org/10.1002/anie.201302968