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One-step preparation of novel conjugated porous polymer with tubular structure.
- Source :
- SCIENCE CHINA Chemistry; Aug2013, Vol. 56 Issue 8, p1112-1118, 7p
- Publication Year :
- 2013
-
Abstract
- A shape-persistent dendritic molecule, tris(4-(2,7-dibromo-9-phenyl-9-fluoren-9-yl)phenyl)amine (TF-6Br), has been readily synthesized in high yield through a concise Friedel-Crafts reaction from triphenylamine and 2,7-dibromo(9-phenyl-fluoren-9-ol). It was further employed as the key building block to achieve the synthesis of conjugated porous polymer via Sonogashira coupling with 1,4-diethynylbenzene. Under experimental reaction conditions, the resulting porous polymer shows exceptionally nanotubular morphology, which further allows for a template-free synthesis of porous carbon nanotubes via thermal treatment at high temperature. The obtained nitrogen-doped carbon nanotubes feature with an improved porosity and high surface area. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 16747291
- Volume :
- 56
- Issue :
- 8
- Database :
- Complementary Index
- Journal :
- SCIENCE CHINA Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 89438829
- Full Text :
- https://doi.org/10.1007/s11426-013-4879-8