Thermochemical properties of hydrazinium dipicrylamine in N-methyl pyrrolidone and dimethyl sulfoxide.

The enthalpies of dissolution for Hydrazinium Dipicrylamine (HDPA) in N-methyl pyrrolidone (NMP) and dimethyl sulfoxide (DMSO) were measured using a RD496-2000 Calvet microcalorimeter at 298.15 K. Empirical formulae for the calculation of the enthalpies of dissolution (Δ H) were obtained from the experimental data of the dissolution processes of HDPA in NMP and DMSO. The linear relationships between the rate ( k) and the amount of substance ( a) were found. The corresponding kinetic equations describing the two dissolution processes were $$ {{\text{d}\alpha } \mathord{\left/ {\vphantom {{\text{d}\alpha} {\text{d}t}}} \right. \kern-0pt} {\text{d}t}} = 10^{ - 2.71}\left( {1 - \alpha } \right)^{1.23} $$ for the dissolution of HDPA in NMP, and $$ {{\text{d}\alpha } \mathord{\left/ {\vphantom {{\text{d}\alpha} {\text{d}t}}} \right. \kern-0pt} {\text{d}t}} = 10^{ - 2.58}\left( {1 - \alpha } \right)^{0.81} $$ for the dissolution of HDPA in DMSO, respectively. [ABSTRACT FROM AUTHOR]