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Surface tension of a square well fluid.

Authors :
Orea, Pedro
Duda, Yurko
Alejandre, José
Source :
Journal of Chemical Physics; 3/22/2003, Vol. 118 Issue 12, p5635, 5p, 1 Chart, 6 Graphs
Publication Year :
2003

Abstract

We performed Monte Carlo simulations in the canonical ensemble on the liquid-vapor interface of a square well fluid with interaction range of λ = 1.5σ. The system contains a liquid slab surrounded by vapor. The surface tension is calculated during simulations by using an original procedure that allows the calculation of the pressure tensor components. The surface tension decreases monotonically with temperature. Coexisting densities and pressure along the liquid-vapor coexistence line have also been obtained and good agreement is found with results calculated from bulk simulations. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
00219606
Volume :
118
Issue :
12
Database :
Complementary Index
Journal :
Journal of Chemical Physics
Publication Type :
Academic Journal
Accession number :
9275643
Full Text :
https://doi.org/10.1063/1.1553751