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Two new halide-containing polyoxometalate-based compounds.
- Source :
- Journal of Coordination Chemistry; Feb2014, Vol. 67 Issue 4, p728-736, 9p
- Publication Year :
- 2014
-
Abstract
- Two new compounds, [CuCl(Phen)(H2O)][PW12O40][4,4′-H2bpy]·1.5H2O (1) and [Cd2(Phen)4Cl2][HPMo12O40](4,4′-bpy) (2) (bpy = bipyridine, Phen = phenanthroline), have been hydrothermally prepared and characterized by IR, UV–vis, XPS, XRD, elemental analysis, cyclic voltammetry analysis, and single-crystal X-ray diffraction analysis. Compound1exhibits a 1-D chain structure constructed from polyoxometalates (POMs) and transition metal complexes, whereas2presents a supramolecular structure constructed from POMs, metal halide clusters, and organic ligands. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 00958972
- Volume :
- 67
- Issue :
- 4
- Database :
- Complementary Index
- Journal :
- Journal of Coordination Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 95477230
- Full Text :
- https://doi.org/10.1080/00958972.2014.890719