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Silver-Catalyzed Decarboxylative Trifluoromethylthiolation of Aliphatic Carboxylic Acids in Aqueous Emulsion.
- Source :
- Angewandte Chemie International Edition; Jun2014, Vol. 53 Issue 24, p6105-6109, 5p
- Publication Year :
- 2014
-
Abstract
- A silver-catalyzed decarboxylative trifluoromethylthiolation of secondary and tertiary carboxylic acids under mild conditions tolerates a wide range of functional groups. The reaction was dramatically accelerated by its performance in an aqueous emulsion, which was formed by the addition of sodium dodecyl sulfate to water. It was proposed that the radical, which was generated from the silver-catalyzed decarboxylation in the 'oil-in-water' droplets, could easily react with the trifluoromethylthiolating reagent to form the product. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 14337851
- Volume :
- 53
- Issue :
- 24
- Database :
- Complementary Index
- Journal :
- Angewandte Chemie International Edition
- Publication Type :
- Academic Journal
- Accession number :
- 96362463
- Full Text :
- https://doi.org/10.1002/anie.201402573