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The microstructure and rheology of a model, thixotropic nanoparticle gel under steady shear and large amplitude oscillatory shear (LAOS).
- Source :
- Journal of Rheology; Sep2014, Vol. 58 Issue 5, p1301-1328, 28p
- Publication Year :
- 2014
-
Abstract
- The microstructure-rheology relationship for a model, thermoreversible nanoparticle gel is investigated using a new technique of time-resolved neutron scattering under steady and timeresolved large amplitude oscillatory shear (LAOS) flows. A 21 vol. % gel is tested with varying strength of interparticle attraction. Shear-induced structural anisotropy is observed as butterfly scattering patterns and quantified through an alignment factor. Measurements in the plane of flow show significant, local anisotropy develops with alignment along the compressional axis of flow, providing new insights into how gels flow. The microstructure-rheology relationship is analyzed through a new type of structure-Lissajous plot that shows how the anisotropic microstructure is responsible for the observed LAOS response, which is beyond a response expected for a purely viscous gel with constant structure. The LAOS shear viscosities are observed to follow the "Delaware-Rutgers" rule. Rheological and microstructural data are successfully compared across a broad range of conditions by scaling the shear rate by the strength of attraction, providing a method to compare behavior between steady shear and LAOS experiments. However, important differences remain between the microstructures measured at comparatively high frequency in LAOS experiments and comparable steady shear experiments that illustrate the importance of measuring the microstructure to properly interpret the nonlinear, dynamic rheological response. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 01486055
- Volume :
- 58
- Issue :
- 5
- Database :
- Complementary Index
- Journal :
- Journal of Rheology
- Publication Type :
- Academic Journal
- Accession number :
- 97880974
- Full Text :
- https://doi.org/10.1122/1.4878378