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MOF-derived nitrogen-doped porous carbon as metal-free catalysts for acetylene hydrochlorination.
- Source :
- Journal of Industrial & Engineering Chemistry; Dec2016, Vol. 44, p146-154, 9p
- Publication Year :
- 2016
-
Abstract
- A series of ZIF-derived nitrogen-doped carbon materials were prepared using melamine as the additional nitrogen sources for acetylene hydrochlorination. The results indicated that the optimal complex of Z 4 M 1 exhibits the highest acetylene conversion of 60% under the reaction conditions of 180 °C, C 2 H 2 gas hourly space velocity (GHSV) = 50 h −1 , V HCl /V C2H2 = 1.15, suggesting a promising metal-free catalyst for acetylene hydrochlorination. It is illustrated that the additions of melamine not only make the complex of Z 4 M 1 displays special morphological structure and proper pore structure, but also adjust the relative content ratio of three nitrogen species in ZIF-derived nitrogen-doped carbon materials. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 1226086X
- Volume :
- 44
- Database :
- Supplemental Index
- Journal :
- Journal of Industrial & Engineering Chemistry
- Publication Type :
- Periodical
- Accession number :
- 118497629
- Full Text :
- https://doi.org/10.1016/j.jiec.2016.08.024