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Synthesis of PtNPs/MWCNT Functionalized with 4-Mercaptophenylboronic Acid for an Electrochemical Sensor of Fructose.

Authors :
Silva-Carrillo, Carolina
Reynoso-Soto, Edgar Alonso
Paraguay-Delgado, Francisco
Alonso-Núñez, Gabriel
Felix-Navarro, Rosa Maria
Source :
Journal of The Electrochemical Society; 2017, Vol. 164 Issue 4, pB86-B91, 6p
Publication Year :
2017

Abstract

Platinum nanoparticles (PtNPs) on multi-wall carbon nanotubes (MWCNT) were functionalized with 4-mercaptophenylboronic acid (4MPB) for electrochemical detection of fructose. The composite nanomaterial was characterized by physicochemical techniques such as TGA and TEM, and electrochemically using the [Fe(CN)<subscript>6</subscript>]<superscript>3-/4-</superscript> as channel ion. Experimental values indicate that this sensor presents high sensitivity and selectivity for electrochemical detection of fructose with the sensitivity of 2.794 x 10<superscript>-5</superscript> A mM<superscript>-1</superscript> in a range of 2.5 to 10 mM using cyclic voltammetry and sensitivity 8.65 Ω mM<superscript>-1</superscript> in range of 0.5 to 10 mM using electrochemical impedance spectroscopy. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
00134651
Volume :
164
Issue :
4
Database :
Supplemental Index
Journal :
Journal of The Electrochemical Society
Publication Type :
Academic Journal
Accession number :
122398538
Full Text :
https://doi.org/10.1149/2.0211704jes