Back to Search
Start Over
Closely packed Si@C and Sn@C nano-particles anchored by reduced graphene oxide sheet boosting anode performance of lithium ion batteries.
- Source :
- Journal of Materials Science & Technology; Oct2021, Vol. 87, p18-28, 11p
- Publication Year :
- 2021
-
Abstract
- [Display omitted] • Si@C/Sn@C/rGO nanocomposite was synthesized via impregnation and hydrogenation reduction. • Si@C/Sn@C/rGO delivers a reversible capacity of 1880 mA h g<superscript>−1</superscript> after 60 cycles and high rate capability. • Double core-shell structure effectively suppresses volume variation of electrodes. • The preparation process is acid-free and environmentally friendly. Both silicon and tin are promising anodes for new generation lithium ion batteries due to high lithium storage capacities (theoretically 4200 mA h g<superscript>−1</superscript> and 992 mA h g<superscript>-1</superscript>, respectively). However, their large volumetric expansions (both are above 300 %) usually lead to poor cycling stability. In this case, we synthesized closely packed Si@C and Sn@C nano-particles anchored by reduced graphene oxide (denoted as Si@C/Sn@C/rGO) by the way of solution impregnation and subsequent hydrogenation reduction. Sn particles with a diameter of 100 nm are coated by carbon and surrounded by Si@C particles around 40 nm in average diameter through the high-resolution transmission electron microscopy. Expansions of Si and Sn are alleviated by carbon shells, and reduced graphene oxide sheets accommodate their volume changes. The prepared Si@C/Sn@C/rGO electrode delivers an enhanced initial coulombic efficiency (78 %), rate capability and greatly improved cycle stability (a high reversible capacity of nearly 1000 mA h g<superscript>−1</superscript> is achieved after 300 cycles at a current density of 1000 mA g<superscript>−1</superscript>). It can be believed that packing Sn@C nano-particles with Si@C relieves the volume expansion of both and releases the expansion stresses. Sn@C particles enhance anode process kinetics by reducing charge transfer resistance and increasing lithium ion diffusion coefficient. The present work provides a viable strategy for facilely synthesizing silicon-tin-carbon composite anode with long life. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 10050302
- Volume :
- 87
- Database :
- Supplemental Index
- Journal :
- Journal of Materials Science & Technology
- Publication Type :
- Periodical
- Accession number :
- 151306890
- Full Text :
- https://doi.org/10.1016/j.jmst.2020.12.075