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Precursor-oriented ultrathin Zr-based gradient coating on Ni-riched cathodes.
- Source :
- Nano Energy; Jan2023, Vol. 105, pN.PAG-N.PAG, 1p
- Publication Year :
- 2023
-
Abstract
- We present a simple and low-cost interfacial precipitation-conversion reaction strategy, which employs the precursors as orientators to coat ultrathin and surface-gradient layers for reserving the structural integrality and stability of particularize materials. Using the typical high-nickel layered cathode (LiNi 0.8 Co 0.15 Al 0.05 O 2 , NCA) as a prototype, we successively processed NCA carbonate oxalate precursors with (NH 4) 2 HPO 4 and ZrOCl 2 solutions to chemically induce Zr species on the NCA surfaces via strong M-PO 4 -Zr interactions (M = Ni, Co). An ultrathin Zr-contained gradient layer is in-situ self-assembled spontaneously and conformably (NCA@ZP) after calcination. The as-designed NCA@ZP cathode delivers a high capacity of 219.7 mA h·g<superscript>−1</superscript>, 23% higher than NCA (179.0 mA h·g<superscript>−1</superscript>) at 0.1 C, and exhibits superior rate capability (128.2 mA h·g<superscript>−1</superscript> capacity at 16 C) and cycling stability. Experimental characterization together with calculation further reveal that the residential Zr element at Li<superscript>+</superscript> sites strengthen the adjacent M-O bonds, inhibiting the oxygen evolution and dissolution of transition metal, buffering the internal strains, stabilizing the cathode-electrolyte interface, improving the electrical conductivity and consequently benefiting the cyclability and rate capability. Such a simple precursor-oriented strategy can be easily scaled-up and extended to various application scenarios who encounter unwanted side-reactions or structural degradation during chemical reactions. [Display omitted] • An ultrathin and completely-covered Zr-based gradient coating layer on the NCA surface is achieved by a simple precursor-oriented strategy based on precipitation conversion reaction and strong M-PO 4 -Zr interactions (M = Ni, Co). • The Zr-contained gradient coating layer can effectively improve the cycling stability and achieve superior rate capability of the NCA cathode. • This precursor-oriented strategy can be easily scaled-up and extended to various application scenarios who encounter structural degradation during cycling. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 22112855
- Volume :
- 105
- Database :
- Supplemental Index
- Journal :
- Nano Energy
- Publication Type :
- Academic Journal
- Accession number :
- 160845262
- Full Text :
- https://doi.org/10.1016/j.nanoen.2022.108000