Back to Search
Start Over
Fe-rich pyrophosphate with prolonged high-voltage-plateaus and suppressed voltage decay as sodium-ion battery cathode.
- Source :
- Nano Energy; Nov2023, Vol. 116, pN.PAG-N.PAG, 1p
- Publication Year :
- 2023
-
Abstract
- Fe-based polyanionic materials are potential cathode candidates for sodium-ion batteries, however, voltage decay and cycling stability become main challenges for practical applications. Besides, the mechanism of phase transition during charge/discharge processes is still unclear. Herein, the Fe-rich phase Na 1.4 Fe 1.3 P 2 O 7 with Na/Fe atom vacancies is constructed, showing robust voltage decay suppression and a larger ratio of the plateau length (6:1) at 3.0 and 2.5 V than that of the conventional Na-rich phase Na 2 FeP 2 O 7 (2.5:1). After 650 cycles at 1 C, the capacity and average voltage retentions of Fe-rich phase are 84 % and 95 %, respectively, much higher than that of Na-rich phase (12 % and 61 %). Furthermore, Mössbauer spectra unveil that, during discharge processes at high voltages, more Fe<superscript>3+</superscript>reduction in Fe-rich phase is the intrinsic reason for larger plateau length and lower voltage decay. Density functional theory (DFT) calculation results demonstrate that the higher reduction ability of Fe<superscript>3+</superscript> in Fe-rich phase at high voltages is due to the better reversibility of the two-phase transition between β-NaFeP 2 O 7 and Fe-rich phase than that between β-NaFeP 2 O 7 and Na-rich phase. These allow Fe-rich phase with higher energy densities, lower voltage decay and better cycling stability at high voltage plateaus. Our work provides a new idea for safe design, low-cost and long cycle life sodium ion cathode battery materials. [Display omitted] • The high voltage discharge platform is effectively prolonged in the Fe-rich phase Na 1.4 Fe 1.3 P 2 O 7. • The capacity and average voltage retentions of the Fe-rich are much higher than that of the Na-rich cathode. • Observed biphasic transition behavior in reaction, and the intermediate phase is identified as β-NaFeP 2 O 7. • The high correlation between phase transition, Fe<superscript>3+</superscript> reduction, and electrochemistry performance is disclosed. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 22112855
- Volume :
- 116
- Database :
- Supplemental Index
- Journal :
- Nano Energy
- Publication Type :
- Academic Journal
- Accession number :
- 172427857
- Full Text :
- https://doi.org/10.1016/j.nanoen.2023.108822