Degradation of phenol by peroxymonosulfate catalyzed by cerium-doped amino-functionalized metal-organic frameworks (NH2-MIL-101 (Fe, Ce)).

As an organic pollutant difficult to be degraded in water bodies, phenol is toxic even at low concentrations. Therefore, studying the degradation technology of phenol is of great significance. In order to investigate the effect of transition metal doping on the performance of oxidative degradation of phenol by the persulfate activated by metal-organic frameworks, the different doping levels of Ce were tested based on the NH 2 -MIL-101(Fe). Then, NH 2 -MIL-101(Fe,Ce) with different Fe/Ce ratios was successfully prepared by solvothermal method. They were characterized by means of XRD, SEM, TEM, XPS and FT-IR. Selecting phenol as the target pollutant, the NH 2 -MIL-101(Fe,Ce)/PMS system was constructed to study the degradation rate. The factors of the different temperature, initial pH, anions, Ce doping ratios, catalyst dosage and PMS concentration were investigated. The mechanism of degradation of phenol for the above system was analyzed through free radical burst test, and the metal ion dissolution of catalytic materials in simulated wastewater treatment process was monitored by ICP-OES instrument. Finally, the intermediate products of phenol in the degradation process were inferred using LC-MS method. The results showed that when the molar ratio of Ce/(Ce+Fe) was 15 %, under the same reaction conditions, NH 2 -MIL-101(Fe,Ce)-15 % (referred to as NM-15 %) had the highest degradation rate for phenol. After the 50 min, phenol could be almostly completely removed, with K value of 0.059 min⁻¹. This system could achieve the efficient degradation of phenol under the range of pH values (pH=3–9). The results of the free radical burst test and the free radical trapping test showed that the dominant oxidising groups were SO 4 ^•−, •OH, •O 2 ⁻ and non-free radical ¹O 2. • NH 2 -MIL-101 (Fe,Ce) was successfully prepared and showed high performance on the removal of phenol. • The removal of phenol by the NH 2 -MIL-101 (Fe,Ce)/PMS system reached 100 % in 60 min. • Free radicals involved in degradation reactions include SO 4 ^•− and •OH. • •O²⁻ and ¹O 2 are also responsible for phenol degradation. • Two Phenol degradation pathways were proposed. [ABSTRACT FROM AUTHOR]