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Picosecond X-ray Absorption Spectroscopy of Photochemical Transient Species in Solution.

Authors :
Castleman, A. W.
Toennies, J. P.
Zinth, W.
Yamanouchi, K.
Corkum, Paul
Jonas, David M.
Miller, R. J. Dwayne.
Weiner, Andrew M.
Khalil, Munira
Marcus, Matthew A.
Smeigh, Amanda L.
McCusker, James K.
Chong, Henry H. W.
Schoenlein, Robert W.
Source :
Ultrafast Phenomena XV; 2007, p722-724, 3p
Publication Year :
2007

Abstract

A photoinduced FeII spin crossover reaction in solution is studied with ultrafast x-ray absorption spectroscopy. The iron-nitrogen bond lengthens by 0.21±0.03 A in the high-spin transient excited state relative to the ground state. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISBNs :
9783540687795
Database :
Supplemental Index
Journal :
Ultrafast Phenomena XV
Publication Type :
Book
Accession number :
33316230
Full Text :
https://doi.org/10.1007/978-3-540-68781-8_231