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Synthesis and Properties of New Trimeric and Tetrameric Tetrathiafulvalenes with Alternate Links.

Authors :
Nakamura, Ken-ichi
Hashimoto, Tomomi
Shirahata, Takashi
Hino, Shojun
Hasegawa, Masashi
Mazaki, Yasuhiro
Misaki, Yohji
Source :
Chemistry Letters; 8/5/2011, Vol. 40 Issue 8, p30-30, 1p
Publication Year :
2011

Abstract

Trimeric and tetrameric TTFs 1 and 2 linked alternately by methylenedithio groups were synthesized. Cyclic voltammetry and spectroelectrochemistry indicated that the dicationic state of tetrameric TTF 2 exhibited the mixed-valence state constructed not by the tetrameric TTF units but by two dimeric mutually independent TTF units. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
03667022
Volume :
40
Issue :
8
Database :
Supplemental Index
Journal :
Chemistry Letters
Publication Type :
Academic Journal
Accession number :
66929826
Full Text :
https://doi.org/10.1246/cl.2011.883