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Separation, Hydrodynamics and Heating Effects in Continuous Annular Electro-Chromatography (CAEC).
- Source :
- Procedia Engineering; Dec2012, Vol. 42, p1755-1772, 18p
- Publication Year :
- 2012
-
Abstract
- Abstract: This article presents investigations to transfer an analytical batch electro-chromatography to a continuous annular electro-chromatography process. In order to study the electro-chromatographic effects of such a process a lab scale planar reference system was manufactured and tested. This planar device represents a fraction of the final annular geometry. An inorganic C8 reversed-phase monolith was filled between two glass plates as stationary phase inside a 1mm gap. The generation of Joule heating during the process was determined by using a contact-free thermal camera system. Additionally, the volume flow rate of the electrolyte was detected at the outlet geometry with a continuous imaging analysis system using the transmitted light method. Finally, a mixture of neutral test substances was used to evaluate the continuous separation and to compare the results of the planar plate with an analytical capillary. The obtained results indicate a uniform electro-osmotic flow as well as a successful separation of the test system and a good agreement between the efficiency of the planar gap and an analytical capillary electro-chromatographic device. [Copyright &y& Elsevier]
Details
- Language :
- English
- ISSN :
- 18777058
- Volume :
- 42
- Database :
- Supplemental Index
- Journal :
- Procedia Engineering
- Publication Type :
- Academic Journal
- Accession number :
- 79487066
- Full Text :
- https://doi.org/10.1016/j.proeng.2012.07.555