Electrochemical degradation of the Disperse Orange 29 dye on a β-PbO2 anode assessed by the response surface methodology.

Abstract: The electrochemical degradation of the Disperse Orange 29 azo dye in a filter-press flow cell using a Ti–Pt/β-PbO₂ as anode was investigated by experimental design for the variables current density, pH, [NaCl], and temperature. The electrochemical system was modeled by the charge required to attain 90% decolorization (Q ⁹⁰) and the chemical oxygen demand removal after 120min of electrolysis (COD ¹²⁰). The best conditions for Q ⁹⁰ were neutral to slightly alkaline solutions with low values of [NaCl] (<1.0gL⁻¹). On the other hand, slightly acidic to neutral conditions with higher values of [NaCl] (1.2–1.7gL⁻¹) yielded the highest COD ¹²⁰ values. These differences were ascribed to the possible formation of organochloride compounds that may lead to erroneous COD values. A total mass loss of only 0.1% was obtained during an accelerated life test of the Ti–Pt/PbO₂ anode. Low levels of [Pb²⁺] were attained in neutral to alkaline conditions [Copyright &y& Elsevier]