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Theoretical study of (FH2X) n ·Y (X=P and As, n =1–4, Y=F−, Cl−, Br−, I−, NO3 − and SO4 2−)...

Authors :
Chen, YiShan
Yao, LiFeng
Lin, XueFei
Source :
Computational & Theoretical Chemistry; May2014, Vol. 1036, p44-50, 7p
Publication Year :
2014

Abstract

Highlights: [•] The anion-binding ability of FH<subscript>2</subscript>As is stronger than that of FH<subscript>2</subscript>P. [•] The binding strength is in the sequence of SO<subscript>4</subscript> <superscript>2−</superscript> >F<superscript>−</superscript> >Cl<superscript>−</superscript> >NO<subscript>3</subscript> <superscript>−</superscript> >Br<superscript>−</superscript> >I<superscript>−</superscript>. [•] The anion-binding strength of pnicogen bonding is comparable to that of hydrogen and halogen bonding. [•] The anion-binding ability of pnicogen bonding can be strengthened through multiple receptor–anion interactions. [Copyright &y& Elsevier]

Details

Language :
English
ISSN :
2210271X
Volume :
1036
Database :
Supplemental Index
Journal :
Computational & Theoretical Chemistry
Publication Type :
Academic Journal
Accession number :
95632122
Full Text :
https://doi.org/10.1016/j.comptc.2014.03.006