Syntheses and Characterisation of Manganese(III) Perchlorate Complexes with Unsymmetrical Schiff Bases

Authors :: Bermejo, M.R.
Perez, M.C.
Fondo, M.
Maneiro, M.
Source :: Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry; August 1997, Vol. 27 Issue: 7 p1009-1024, 16p
Publication Year :: 1997
Abstract: AbstractA series of unsymmetrical tridentate dianionic Schiff bases derived from substituted salicylaldehyde and ethanol and propanolamine were prepared and characterised by elemental analyses, IR and 1H NMR spectroscopy. The interaction of these bases with Mn(ClO4)2.6H2O has been studied, leading to the preparation of manganese(III) perchlorate complexes. All the Schiff base ligands H2L yield 1:1 compounds [MnL(H2O)2]CIO4.nH2O (n = 1–3). The resultant complexes were characterised by elemental analyses, IR spectroscopy and magnetic measurements.Referee I: L. T. BoucherReferee II: J. H. Worrell

Language :: English
ISSN :: 15533174 and 15533182
Volume :: 27
Issue :: 7
Database :: Supplemental Index
Journal :: Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry
Publication Type :: Periodical
Accession number :: ejs11367560
Full Text :: https://doi.org/10.1080/00945719708000243

Full Text Access

Tools