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[PtCl<INF>3</INF>(C<INF>2</INF>H<INF>4</INF>)]<SUP>-</SUP>[(S,S)-(PhMeCH)<INF>2</INF>NH<INF>2</INF>]<SUP>+</SUP>: A New and Versatile Ionic Organometallic Chiral Derivatizing Agent for the Determination of the Enantiomeric Composition of Chiral Unsaturated Compounds by <SUP>195</SUP>Pt NMR Spectroscopy
- Source :
- Organic Letters; June 2000, Vol. 2 Issue: 13 p1795-1798, 4p
- Publication Year :
- 2000
-
Abstract
- <UFIGR ID="ol0000509n00001">The ionic complex [PtCl<INF>3</INF>(C<INF>2</INF>H<INF>4</INF>)]<SUP>-</SUP>[(S,S)-(PhMeCH)<INF>2</INF>NH<INF>2</INF>]<SUP>+</SUP> containing a chiral secondary amine is a new and versatile chiral derivatizing agent (CDA) for the determination of the enantiomeric composition of several unsaturated compounds including simple olefins: the diastereoisomeric mixtures arising from the exchange of ethylene by the unsaturated analytes are easily detected by <SUP>195</SUP>Pt NMR spectroscopy.
Details
- Language :
- English
- ISSN :
- 15237060 and 15237052
- Volume :
- 2
- Issue :
- 13
- Database :
- Supplemental Index
- Journal :
- Organic Letters
- Publication Type :
- Periodical
- Accession number :
- ejs1160186