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Electronic Properties of Ba-Intercalated Fullerides

Authors :
Iwasa, Y.
Chen, X.H.
Takenobu, T.
Mitani, T.
Source :
Molecular Crystals and Liquid Crystals; March 2000, Vol. 340 Issue: 1 p583-586, 4p
Publication Year :
2000

Abstract

AbstractRaman spectra have been measured on BaxC60binary systems for x=3, 4 and 6. The pentagonal pinch Ag(2) mode exhibits a softening in an approximately proportional manner to the formal valence of C60molecule. This result suggests that the valence of C60in Ba doped systems are understood by the naive ionic crystal model based on Ba2+. The broader Raman peaks in superconducting Ba4C60indicates that the electron-phonon interaction is considerably large comparing to those for Ba3C60and Ba6C60.

Details

Language :
English
ISSN :
15421406 and 15635287
Volume :
340
Issue :
1
Database :
Supplemental Index
Journal :
Molecular Crystals and Liquid Crystals
Publication Type :
Periodical
Accession number :
ejs11602749
Full Text :
https://doi.org/10.1080/10587250008025529