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Highly Efficient MolybdenumIICatalyzed Intramolecular Allylic Alkylation of Arenes

Authors :
Bandini, Marco
Eichholzer, Astrid
Kotrusz, Peter
UmaniRonchi, Achille
Source :
Advanced Synthesis & Catalysis; March 2008, Vol. 350 Issue: 4 p531-536, 6p
Publication Year :
2008

Abstract

The Friedel–Craftstype intramolecular allylic alkylation of simple arenes is performed in the presence of a catalytic amount of MoII CO4Br222.5 mol%. The moisturetolerant protocol provided a mild and direct access to a large library of functionalized 4vinyl1,2,3,4tetrahydronaphthalenes in high yields.

Details

Language :
English
ISSN :
16154150 and 16154169
Volume :
350
Issue :
4
Database :
Supplemental Index
Journal :
Advanced Synthesis & Catalysis
Publication Type :
Periodical
Accession number :
ejs13887902
Full Text :
https://doi.org/10.1002/adsc.200700607