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Nucleophilic substitution in iodonium derivatives of indole

Authors :
Ermolenko, M. S.
Budylin, V. A.
Kost, A. N.
Source :
Chemistry of Heterocyclic Compounds; July 1978, Vol. 14 Issue: 7 p752-754, 3p
Publication Year :
1978

Abstract

3-Indolylphenyliodonium tosylate and trifluoroacetate were synthesized, and their reaction with halide anions was investigated. It is shown that the iodonium grouping is replaced by halogen in all cases. 3-Fluoroindole was synthesized for the first time. The mechanism of the reaction is discussed, and data from the mass spectra of the 3-haloindoles obtained are presented.

Details

Language :
English
ISSN :
00093122 and 15738353
Volume :
14
Issue :
7
Database :
Supplemental Index
Journal :
Chemistry of Heterocyclic Compounds
Publication Type :
Periodical
Accession number :
ejs16749383
Full Text :
https://doi.org/10.1007/BF00471643