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Synthesis and molecular structure of [{Pd<SUB>2</SUB>(CH<SUB>2</SUB>C<SUB>6</SUB>H<SUB>4</SUB>P(o-tolyl)<SUB>2</SUB>-κC,P)<SUB>2</SUB>(μ<SUB>3</SUB>-3,5-dmpz-N,N',C<SUP>4</SUP>)<SUB>2</SUB>Ag(μ-ClO<SUB>4</SUB>)}<SUB>2</SUB>] (3,5-dmpz = 3,5-dimethylpyrazolato), a silver derivative showing unprecedented η<SUP>1</SUP>-azolato coordination

Authors :
Falvello, Larry R.
Forniés, Juan
Martín, Antonio
Navarro, Rafael
Sicilia, Violeta
Villarroya, Pablo
Source :
Chemical Communications; November 21, 1998, Vol. 1998 Issue: 22 p2429-2430, 2p
Publication Year :
1998

Abstract

The reaction of [Pd&lt;SUB&gt;2&lt;/SUB&gt;(CH&lt;SUB&gt;2&lt;/SUB&gt;C&lt;SUB&gt;6&lt;/SUB&gt;H&lt;SUB&gt;4&lt;/SUB&gt;P(o-tolyl)&lt;SUB&gt;2&lt;/SUB&gt;-κC,P)&lt;SUB&gt;2&lt;/SUB&gt;(μ-3,5-dmpz)&lt;SUB&gt;2&lt;/SUB&gt;] (1) with AgClO&lt;SUB&gt;4&lt;/SUB&gt; renders [{Pd&lt;SUB&gt;2&lt;/SUB&gt;(CH&lt;SUB&gt;2&lt;/SUB&gt;C&lt;SUB&gt;6&lt;/SUB&gt;H&lt;SUB&gt;4&lt;/SUB&gt;P(o-tolyl)&lt;SUB&gt;2&lt;/SUB&gt;-κC,P)&lt;SUB&gt;2&lt;/SUB&gt;(μ&lt;SUB&gt;3&lt;/SUB&gt;-3,5-dmpz-N,N&#39;,C&lt;SUP&gt;4&lt;/SUP&gt;)&lt;SUB&gt;2&lt;/SUB&gt;Ag(η&lt;SUP&gt;2&lt;/SUP&gt;-μ-ClO&lt;SUB&gt;4&lt;/SUB&gt;)}&lt;SUB&gt;2&lt;/SUB&gt;] (2), a palladium–silver derivative displaying an unprecedented dmpz bridging ligand η&lt;SUP&gt;1&lt;/SUP&gt; bonded to the Ag centers, involving only the C&lt;SUP&gt;4&lt;/SUP&gt; atom of each dmpz ligand.

Details

Language :
English
ISSN :
13597345 and 1364548X
Volume :
1998
Issue :
22
Database :
Supplemental Index
Journal :
Chemical Communications
Publication Type :
Periodical
Accession number :
ejs1697580

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