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Nitrous oxide decomposition active site on Ni–MgO catalysts characterized by X-ray absorption fine structure spectroscopy

Authors :
Izumi, Yasuo
Shimizu, Takehiro
Kobayashi, Takaaki
Aika, Ken-ichi
Source :
Chemical Communications; June 21, 2000, Vol. 2000 Issue: 12 p1053-1054, 2p
Publication Year :
2000

Abstract

A contracted Ni<SUP>2+</SUP> coordination site distorted in the direction of Ni&z.dotdot;Mg and Ni&z.dotdot;Ni was found to be responsible for catalytic N<SUB>2</SUB>O decomposition when Ni<SUP>2+</SUP> is diluted in a MgO matrix (Ni<SUP>2+</SUP>/Mg<SUP>2+</SUP> atomic ratio ≈ 1.0) based on a local structure study by nickel K-edge X-ray absorption fine structure spectroscopy.

Details

Language :
English
ISSN :
13597345 and 1364548X
Volume :
2000
Issue :
12
Database :
Supplemental Index
Journal :
Chemical Communications
Publication Type :
Periodical
Accession number :
ejs1699340