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Spin Canting in a CobaltII Radical Complex with an Acentric Counter Anion
- Source :
- European Journal of Inorganic Chemistry; November 2008, Vol. 2008 Issue: 31 p4851-4855, 5p
- Publication Year :
- 2008
-
Abstract
- CobaltII radical complexes with centric and acentric counter anions, [CoClbisimpyMeOH2]X [bisimpy = 2,6bis4′,4′,5′,5′tetramethyl4′,5′dihydro1′Himidazol1′oxyl2′ylpyridine; X = PF61, and ClO42], crystallize in the centrosymmetric and polar space groups, respectively. Compound 1is paramagnetic, whereas spin canting in 2leads to a metamagnetic transition with a critical field of 1300 Oe at 1.8 K. © WileyVCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008
Details
- Language :
- English
- ISSN :
- 14341948 and 10990682
- Volume :
- 2008
- Issue :
- 31
- Database :
- Supplemental Index
- Journal :
- European Journal of Inorganic Chemistry
- Publication Type :
- Periodical
- Accession number :
- ejs17238729
- Full Text :
- https://doi.org/10.1002/ejic.200800824