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Pronounced Electrochemical Amphotericity of a Fused Donor–Acceptor Compound: A Planar Merge of TTF with a TCNQ‐Type Bithienoquinoxaline
- Source :
- Chemistry - A European Journal; January 2009, Vol. 15 Issue: 1 p63-66, 4p
- Publication Year :
- 2009
-
Abstract
- Narrowing the gap: A compactly fused π‐conjugated molecule combines a high‐lying HOMO with a low‐lying LUMO (Eox−Ered=0.52 eV) and a fairly low‐lying LUMO+1 on the bridging unit, giving rise to strong optical charge‐transfer transitions. A facile electron transfer has been observed by EPR and NMR spectroscopies.
Details
- Language :
- English
- ISSN :
- 09476539 and 15213765
- Volume :
- 15
- Issue :
- 1
- Database :
- Supplemental Index
- Journal :
- Chemistry - A European Journal
- Publication Type :
- Periodical
- Accession number :
- ejs17632575
- Full Text :
- https://doi.org/10.1002/chem.200802011