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Metal ion initiated halogenation reaction of N-haloamines

Authors :
Minisci, F.
Gardini, G. P.
Bertini, F.
Source :
Canadian Journal of Chemistry; February 1970, Vol. 48 Issue: 4 p544-545, 2p
Publication Year :
1970

Abstract

The metal ion catalyzed chlorination of 1-chlorobutane, 1-chlorohexane, methyl-pentanoate, and methyl-heptanoate by protonated N-chloroamines proceeds by a free radical chain mechanism and the chain carrying species was shown not to be a chlorine atom, but an amino radical cation.

Details

Language :
English
ISSN :
00084042 and 14803291
Volume :
48
Issue :
4
Database :
Supplemental Index
Journal :
Canadian Journal of Chemistry
Publication Type :
Periodical
Accession number :
ejs19726423
Full Text :
https://doi.org/10.1139/v70-090